Hi Jordan,
The first thing to come to mind is that it is something to do with the way the .csv file is getting parsed into Excel. This could be being driven by the participant's response in a free-response type item (e.g., thought listing, essay, fill-in-the-blank), especially if they have put a comma or new line in their response.
Is there a whole extra participant in the byvariable file, or just an additional blank line? If the former, is there anything notable about their responses (or maybe the responses of the participant before them)?
If you right-click the file, you can open it up in Notepad, and see whether the problematic participant is showing a notably different formatting to the others (e.g., extra commas or spreading responses over multiple lines). The file will be a list of numbers separated by commas. It can be a little hard to read but each participant will have the file directory for the experiment listed, which is a useful landmark for orientating yourself.
Hope this helps. Let me know if anything isn't clear.